Questions
Reduction potential of chlorine electrode will be highest at 298K and 1 bar pressure of Chlorine when Platinum electrode is immersed in
detailed solution
Correct option is C
The reduction reaction involved is: Cl2+2e-1→2Cl-1; QR=[Cl-1]2PCl2 Nernst equation for the electrode potential is E=E0-2.303RTnFlog10QR=E0-0.05912log10[Cl-1]PCl2 Lower the concentration of [Cl-1], greater will be the electrode potential.In general, reduction potential of non-metal electrode increases with decrease in the concentration of electrolyte. Hence, reduction potential of chlorine electrode is highest when inert Pt electrode is immersed in 0.001M HCl.Talk to our academic expert!
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