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Q.

The reduction potential of hydrogen half-cell will be negative if

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a

p(H2)=1 atm and H+=2.0 M

b

p(H2)=1 atm and H+=1.0 M

c

p(H2)=2 atm and H+=1.0 M

d

p(H2)=2 atm and H+=2.0 M

answer is C.

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Detailed Solution

Reduction hydrogen half-cell is H+zMPt(H2);Pressure pH2Half-cell reaction is 2H+aq+2e-→H2(g)Reaction quotient =Q=pH2/H+2and n=2Ecello=Eredo-0.0591nlog Q=0-0.05912log QEredo=0.00 Vfor standard hydrogen electrode If Q>1,then Eredo=-ve Thus, correct answer is (c ).
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The reduction potential of hydrogen half-cell will be negative if