Q.

Regarding batteries, some reactions are given below. The false combination is

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a

MnO2+NH4++e-→MnO(OH)+NH3   .   .   .   Cathodic reaction in dry cell

b

Zn-Hg+2OH-→ZnO+H2O+Hg+2e-  .   .   .  Anodic reaction in mercury cell

c

Pb+SO4-2→PbSO4+2e-  .   .   .  Anodic reaction in lead storage battery during dischage

d

2H2O+2e-→H2+4OH- .    .    .   Cathodic reaction in H2-O2 fuel cell

answer is D.

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Detailed Solution

In  H2-O2  fuel cell At cathode :     O2+2H2O+2e-→4OH-
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Regarding batteries, some reactions are given below. The false combination is