Q.
Regarding the complex NiCO4, false statement is
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a
It is a tetrahedral complex
b
Nickel-carbon bond acquires double bond character due to backbonding
c
It is a paramagnetic complex
d
Carbon-Oxygen bond is longer than in carbon monoxide
answer is C.
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Detailed Solution
It is a diamagnetic, tetrahedral complex;Back bonding occurs due to the donation of an electron pair from metal to anti bonding pi molecular orbital of CO;M-C bond acquires double bond character;C-O bond length will be intermediate of 2 and 3.Thus the C-O bond in NiCO4 is longer than in carbon monoxide (bond order 3);
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