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Q.

Regarding the complex NiCO4, false statement is

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a

It is a tetrahedral complex

b

Nickel-carbon bond acquires double bond character due to backbonding

c

It is a paramagnetic complex

d

Carbon-Oxygen bond is longer than in carbon monoxide

answer is C.

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Detailed Solution

It is a diamagnetic, tetrahedral complex;Back bonding occurs due to the donation of an electron pair from metal to anti bonding pi molecular orbital of CO;M-C bond acquires double bond character;C-O bond length will be intermediate of 2 and 3.Thus the C-O bond in  NiCO4 is longer than in carbon monoxide (bond order 3);
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Regarding the complex NiCO4, false statement is