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Q.

Regarding the -NH2 group of aniline, correct statement is

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a

It shows +M effect only

b

It shows -I effect only

c

It shows -I, -M effect

d

It shows -I, +M effect

answer is D.

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Detailed Solution

In aniline lone pair is less available for donation due to resonance. Aniline is less basic than ammonia.Due to higher electronegativity of nitrogen as compared to carbon, -NH2 gp shows “-I” effect.Due to the donation of lonepair to benzene ring, -NH2 gp shows “+M” effect .+M effect >>> -I effect, it is highly activating group towards ESR.
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Regarding the -NH2 group of aniline, correct statement is