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Q.

Regarding nitration of benzene,  false statement is

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a

In nitration mixture,  HNO3 acts as base

b

N+O2   is the electrophile

c

Above 60oC , m-dinitro benzene is obtained

d

Arenium ion is aromatic and stabilizes through resonance.

answer is D.

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Detailed Solution

Nitric acid behaves like  base in presence of a stronger acid like sulphuric acidArenium ion (or) σ – complex is not aromatic due to the presence of sp3 carbon but it can stabilize through resonance.
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