Regarding nitration of benzene, false statement is
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a
In nitration mixture, HNO3 acts as base
b
N+O2 is the electrophile
c
Above 60oC , m-dinitro benzene is obtained
d
Arenium ion is aromatic and stabilizes through resonance.
answer is D.
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Detailed Solution
Nitric acid behaves like base in presence of a stronger acid like sulphuric acidArenium ion (or) σ – complex is not aromatic due to the presence of sp3 carbon but it can stabilize through resonance.