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Q.

Regarding Reimer-Tiemann reaction of phenol with CHCl3 in presence of NaOH the incorrect statement is

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a

:CCl2 is the electrophile

b

c

p-hydroxy benzaldehyde is the minor product

d

Phenoxide is less reactive than phenol towards electrophilic substitution

answer is D.

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Detailed Solution

In phenoxide ion there is no charge separation.In phenol there is charge separation. Stability of phenoxide > phenol. Electron density on benzene ring is more in phenoxide. Electrophilic attack is more easly.
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