Q.

Regarding the structure of Al2Cl6 (g) , false statement is

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a

It contains two 3-centered-2-electron bridges

b

It contains two dative bonds

c

Al-Clb-Al is 102°

d

Clb-Al-Clb is 79°

answer is A.

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Detailed Solution

There are no 3-centered-2-electron bridges in Al2Cl6(g). It has two 3-centered-4-electron bridges involving dative bonds.
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Regarding the structure of Al2Cl6 (g) , false statement is