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Q.

The relative reactivity of 1oH,  2oH  and 3oH in bromination reaction has been found to be 1 : 82 : 1600 respectively. In the reactionThe percentage yields of the products (A) and (B) respectively are expected to be

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a

99.4 %, 0.6 %

b

50 %, 50 %

c

0.6 %, 99.4 %

d

80 %, 20 %

answer is A.

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Detailed Solution

1600 x 1 : 9 x 1 (since 9 primary H are present in B)% of A = 16001609 × 100 = 99.44%% of B = 91609 × 100 = 0.6%
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