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Q.

The resonance energy of N2O from the following data is _______ΔfH∘ of N2O=82kJmol−1eN≡N=946kJmol−1eN=N=418kJmol−1eO=O=498kJmol−1eN=O=607kJmol−1

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answer is -88.

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Detailed Solution

Given, N2+12O2→N2O;ΔexpH=82kJAlso, using bond energy data for structure of N2O as N = N = O,  the Δcal H for N2O is given below, ΔcalH=B.E . data of formation +B.E . data of dissociation ΔcalH=−eN=N+eN=0+eN≡N+12×eO=0=−[418+607]+946+12×498=+170kJ∴ Resonance energy =Exp.ΔH− calculated ΔH=82−170=−88kJ
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