For the reversible reaction, A+B⇌C+D taking place in one litre vessel at 450 K, initial moles of A and B are equal. If the number of moles of A at equilibrium are double the number of moles of C at equilibrium then the equilibrium constant of the reaction is equal to
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Detailed Solution
A + B ⇌ C + D; Initial moles 1 1 - -; Moles at Eqbm 1-x 1-x x x; Given 1-x=2x; x=13; ∆n=0 for the process, volume of the vessel has no effect in the calculation of Kc; Kc=x21-x2=0.25