Q.

In the reversible reaction  the concentration of fluoride ions was made halved, then equilibrium concentration of Ca+2

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answer is 3.

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Detailed Solution

CaF2s⇌Caaq+2+2Faq- k=Ca+2F-2 [F-] is halvedto keep KC constat [Ca+2] must be increased by 4 times
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In the reversible reaction  the concentration of fluoride ions was made halved, then equilibrium concentration of Ca+2