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Q.

Right order of acidic strength is

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a

CH2ClCOOH>HCOOH>C2H5COOH>CH3COOH

b

CH2ClCOOH>HCOOH>CH3COOH>C2H5COOH

c

C2H5COOH>CH3COOH>HCOOH>CH2ClCOOH

d

HCOOH>CH2ClCOOH>CH3COOH>C2H5COOH

answer is B.

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Detailed Solution

Presence of electron withdrawing groups (like halogens, -NO2 , -CN…etc.) stabilizes the carboxylate anion and strengthens the acid.Presence of electron donating group (like -CH3 , -C2H5….etc.) destabilizes the carboxylate anion and weakens the acid.
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