S2O3-2→H+SO4-2. Equivalent weight of S2O3-2 ( M = Molar mass)
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a
M4
b
M8
c
M2
d
M
answer is B.
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Detailed Solution
O.S of sulphur atom in thiosulphate ion and sulphate ion is +2 and +6 respectively.n-factor = 2(6-2) = 8 ;Alternatively O.states of two sulphur atoms in thiosulphate ion are -2 and +6 whereas in sulphate ions both sulphur atoms have +6 state.Thus change in O.S is -2→+6 …change in O.S = 8 ;n - factor = 8Eq.wt =M8