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Q.

SbF5 reacts with XeF4 and XeF6 to form ionic compounds XeF3+SbF6−and XeF5+SbF6− then molecular shape of XeF3+ion and XeF5+ion respectively :

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a

Square pyramidal, T-shaped

b

Bent-T-shape, square pyramidal

c

See-saw, square pyramidal

d

Square pyramidal, see-saw

answer is B.

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Detailed Solution

XeF3+:Bent-T-shape (sp3d-hybridisation)    XeF3+:Square pyramidal (sp3d2-hvbridisation)
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SbF5 reacts with XeF4 and XeF6 to form ionic compounds XeF3+SbF6−and XeF5+SbF6− then molecular shape of XeF3+ion and XeF5+ion respectively :