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Q.

Select the correct order of magnetic moment (in BM) from the following options: I. MnCl42−  II. CoCl42  III. Fe(CN)64−

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a

I > II > III

b

III > II > I

c

III > I > II

d

I > III > II

answer is A.

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Detailed Solution

MnCl42−:P>Δt; d5-system  (weak field ligand) (n=5)μeff=5.9BMCoCl42−:P>Δt; d7-system  (weak field liganld) (n=3)μeff=3.89BMFe(CN)64:P<Δ0; d6-system  (strong field ligand) (n=0)μeff=0BM
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