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Q.

Select correct statement for Cr⋅6NH3⋅Cl3 and Cr⋅5NH3⋅Cl3

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a

In both complex compounds secondary valency is satisfied by only NH3

b

In both complex compounds Cl- are satisfying only primary valency

c

In both complex compounds primary valency is satisfied by only Cl-

d

In both complex compounds all Cl- are ionizable

answer is C.

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Detailed Solution

Cr⋅6NH3⋅Cl3⟶CrNH36Cl3 Secondary valency'6'.satisfied by onlyNH3, all Cl- satisfy only primary valency. Cr⋅NNH3⋅Cl3⟶CrNH35ClCl2  Secondary valency' 6 'satiesfied by five NH3 and one Cl−while all three Cl−satify primary valency.
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