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Q.

Select the correct statement for the equilibrium under standard conditions:H2O(s)⇌H2O(l);ΔS1oH2O(l)⇌H2O(v);ΔS2oH2O(s)⇌H2O(v);ΔS3o

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a

ΔS30>ΔS10

b

ΔS2o≫ΔS1o

c

ΔS30>ΔS20

d

ΔS1>ΔS30

answer is A.

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Detailed Solution

H2O(s) has more ordered arrangement. Also, ΔS2o=SH2O(v)0−SH2O(l)oΔS10=SH2O(l)o−SH2O(s)o∴SH−00 is maximum and this ΔS20≫≫ΔS10.
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