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Q.

Select the correct statements.

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a

XeO3 reacts with KI in acidic medium to give I3⊖ and I2

b

XeO3 disproportionate in basic medium

c

Perxenate XeO64 disproportionate in basic medium.

d

XeF6 reacts with glass

answer is .

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Detailed Solution

(1) (i) XeO3+9I⊖+6H⊕⟶Xe+3H2O+3I3⊖ (ii) XeO3+6I⊖+6H⊕⟶Xe+3H2O+3I2 Correct (2) It does not disproportionate in basic medium, but gives hydrogen xenate ion.XeO3+OH⊖⟶HXeO4⊖(3) Correct (3)Hydrogen xenate ion HXeO4⊖ disproportionate in basic medium.HXeO4+6−+2OH−⟶XeO64−+Xe+O2+2H2O
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