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a
MnO2 dissolves in conc. HCl but does not form Mn4+ ion
b
MnO42− is strongly oxidizing and stable only in very strong alkali.
c
KMnO4 does not act as oxidrzingagent in basic medium
d
Decomposition of acidic KMnO4 is not catalysed by sunlight.

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detailed solution

Correct option is

(1) MnO2+4HCl⟶MnCl2+Cl2+2H2O   It dilute alkali, water or acidic solution MnO42− dirptoportionate also Correct (3)MnO4⊖ acts as an oxidizing agent in basic medium. MnO4⊖+2H2O+3e−⟶MnO2+4OH⊖E∘=1.23VCorrect (4)Decomposition of acidic KMnO4 is catalyzed by sunlight4MnO4⊖+4H⊕⟶4MnO2+2H2O+3O2

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Similar Questions

This section contains questions each with two columns-I and II. Match the items given in column I with that in column II.

 

 

Column I Column II
a.Nip.Elements having same number
of unpaired electron in their
dispositive in column I
b.Naq.At least 13 electrons are having
magnetic quantum number 'zero'
c.Mnr.Atom is paramagnetic
d.Pds.Element is not transition element
  t.Element having pseudo inert gas
configuration in its dispositive cation
 


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