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Q.

Select the incorrect statement

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a

The presence of a hydroxyl group on the benzene ring in phenol stabilises the arenium cation through delocalisation

b

The presence of a cyano group on the benzene ring in benzonitrile destabilises the arenium cation

c

Electron donating groups are usually activating groups

d

toluene is less reactive than benzene towards electrophilic substitution reaction

answer is D.

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Detailed Solution

.methyl group in toluene is ring activating group, due to positive inductive effect
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