Q.
Select the incorrect statement:
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a
The higher oxidation state for d-block elements is most stable with F
b
The bond strength order of the following ions is: Zn22+>Hg22+>Cd22+
c
The ionic size of the following ions is: Mn2+>Fe2+>Co2+>Ni2+
d
Mn2O7 exists but MnF7 does not
answer is B.
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Detailed Solution
Correct (2):Hg22+>Cd22+>Zn22+Due to ineffective shielding of 4f electrons, bond strength is maximum for Hg22+ i.e., Hg⊕−Hg⊕Explanation:(1) Due to high lattice or high bond energy for the higher covalent compounds e.g.; in CrF6 and VF6.(3) Along the 3d series. size decreases, due to increase in Zeff.(4) Due to ability of oxygen to form (pπ- dπ) mtltiple bonding, i.e., vacant 3d orbitals of Mn overlap with 2p orbitals of oxygen.
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