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Q.

Select the incorrect statement:

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a

The higher oxidation state for d-block elements is most stable with F

b

The bond strength order of the following ions is: Zn22+>Hg22+>Cd22+

c

The ionic size of the following ions is: Mn2+>Fe2+>Co2+>Ni2+

d

Mn2O7 exists but MnF7 does not

answer is B.

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Detailed Solution

Correct (2):Hg22+>Cd22+>Zn22+Due to ineffective shielding of 4f electrons, bond strength is maximum for Hg22+ i.e., Hg⊕−Hg⊕Explanation:(1) Due to high lattice or high bond energy for the higher covalent compounds e.g.; in CrF6 and VF6.(3) Along the 3d series. size decreases, due to increase in Zeff.(4) Due to ability of oxygen to form (pπ- dπ) mtltiple bonding, i.e., vacant 3d orbitals of Mn overlap with 2p orbitals of oxygen.
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Select the incorrect statement: