Q.
Select the percentage in which these aminederivatives are formed in the reaction mixture along with the reason.
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a
I→2% II→47% III→51%In the acidic medium, aniline is protonated to form the anilinium ion which is ortho directing
b
I→51% II→2% III→47%In the acidic medium, aniline is protonated to form the anilinium ion which ts para directing
c
II→51% II→47% III →2%In the acidic medium, aniline is protonated to form the anilinium ion which ts meta directing
d
I→50% II→20% III→20%In acidic medium aniline is protonated to form the anilinium ion which is ortho directing
answer is C.
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Detailed Solution
In the strongly acidic medium, aniline is protonated to form the anilinium ion which is meta-directing. That is why besides the ortho and para-derivatives, significant amount of meta-derivative is also formed.
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