Q.

Select the percentage in which these aminederivatives are formed in the reaction mixture along with the reason.

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a

I→2% II→47% III→51%In the acidic medium, aniline is protonated to form the anilinium ion which is ortho directing

b

I→51% II→2% III→47%In the acidic medium, aniline is protonated to form the anilinium ion which ts para directing

c

II→51% II→47% III →2%In the acidic medium, aniline is protonated to form the anilinium ion which ts meta directing

d

I→50% II→20% III→20%In acidic medium aniline is protonated to form the anilinium ion which is ortho directing

answer is C.

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Detailed Solution

In the strongly acidic medium, aniline is protonated to form the anilinium ion which is meta-directing. That is why besides the ortho and para-derivatives, significant amount of meta-derivative is also formed.
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