Select the rate law that corresponds to data shown for the following reaction A + B → products.
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a
Rate =k[B]3
b
Rate =k[B]4
c
Rate =k[A][B]3
d
Rate =k[A]2[B]2
answer is A.
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Detailed Solution
From data 1 and 3, it is clear that keeping (B) constant, [A] is doubled, rate remains unaffected. Hence rate is independent of [A]. From 1 and 4, keeping [A] constant, [B] is doubled, rate become 8 times. Hence rate ∝B3.