The shape/ structure of XeF5− and XeO3F2, respectively, are:

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octahedral and square pyramidal

pentagonal planar and trigonal bipyramidal

trigonal bipyramidal and trigonal bipyramidal

trigonal bipyramidal and pentagonal planar

answer is B.

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Detailed Solution

XeF5− has 2 lone pairs + 5 bond pairs = 7 hybrid orbitals ⇒sp3d3hybridization with 2 lone pairs ⇒ Pentagonal planar. XeO3F2 has zero lone pairs + 5 bond pairs = 5 hybrid orbitals ⇒sp3d hybridization ⇒trigonal bypyramidal

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