Q.

A silver electrode in contact with 1M AgNO3 solution is diluted by 100 times. The true statement about the process is

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a

Reduction potential increases by 0.0591 V

b

Reduction potential decreases by 0.0591 V

c

Reduction potential increases by 0.118 V

d

Reduction potential decreases by 0.118 V

answer is D.

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Detailed Solution

E1=Eo+0.05911log1E1=Eo  .  .  .  .  1E2=Eo+0.05911log1100E2=E0+0.05911log 10-2E2=Eo−20.0591  .  .  .  2Reduction potential decreases by 0.118V
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A silver electrode in contact with 1M AgNO3 solution is diluted by 100 times. The true statement about the process is