First slide

Solubility product(KSP)

Question

Silver nitrate solution is gradually added to an aqueous solution containing 0.01 M each of chloride, bromide and iodide ions. The correct sequence in which the halides will be precipitated is

Easy

A

Bromide, Chloride iodide
B

Iodide, chloride, bromide
C

Iodide, bromide, chloride
D

Bromide chloride

Solution

The $K_{SP}$ values are in the order :
AgCl > AgBr > AgI
Lesser the $K_{sp}$ , less is solubility and easily precipitated Down the group hydration of ion decreases, so solubility decreases and precipitation increases

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