Q.

Silver nitrate solution is gradually added to an aqueous solution containing 0.01 M each of chloride, bromide and iodide ions. The correct sequence in which the halides will be precipitated is

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a

Bromide, Chloride iodide

b

Iodide, chloride, bromide

c

Iodide, bromide, chloride

d

Bromide chloride

answer is C.

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Detailed Solution

The KSP values are in the order :AgCl > AgBr > AgILesser the Ksp, less is solubility and easily precipitated Down the group  hydration of ion decreases, so solubility decreases and precipitation increases
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Silver nitrate solution is gradually added to an aqueous solution containing 0.01 M each of chloride, bromide and iodide ions. The correct sequence in which the halides will be precipitated is