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Q.

For  SO2Cl2g→SO2g+Cl2g, Pressure of  SO2Cl2g changed from 5 atm to 4 atm in 10 min. Then, pressure of SO2Cl2 at the end of 30 minutes will be (in atm)

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Detailed Solution

Decomposition of SO2Cl2g→SO2g+Cl2g is a first order reactionFor same reaction as long as temperature is kept constant rate constants remains same.K10min=k30min2.30310log54=2.30330log5p3log5-log4=log5-logp logp=0.408 p=100.408=2.558≅2.56atm
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