For SO2Cl2g→SO2g+Cl2g,Pressures of SO2Cl2g at t = 0 and t =20 minutes respectively are 700 mm & 350 mm. When logp°p is plotted against time (t), slope equals to
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a
1.505×10-2 s-1
b
1.202×10-3min-1
c
1.505×10-2min-1
d
0.3465min-1
answer is C.
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Detailed Solution
K=2.303tlogp°p logp°p=K2.303×t The equation is of type y=mx,slope =k2.303 k=2.30320log700350=2.303×0.301020 slope=2.303×0.301020×12.303=1.505×10-2min-1