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Q.

Sodium metal is produced commercially by the electrolysis of molten sodium chloride and chlorine is produced as a by product. How many litres of chlorine at 1.8 atm and 27° C will be produced if a current of 1.0 × 103 A is passed through NaCl (l) for 9.65 hr.?

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a

2463

b

460

c

1800

d

1231.6

answer is A.

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Detailed Solution

equivalents of Cl2 produced =1000×9.65×360096500=360moles of Cl2 =180  so V=nRTP⇒180×0.0821×3001.82463 L
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