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Q.

Sodium stearate forms associated colloids

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a

Due to association of Na+ ions

b

Due to dissociation of stearate ion

c

Due to orientation of hydrocarbon chain towards centre of the micelle and COO– groups towards water

d

Due to orientation of COO– groups towards center of the micelle and hydrocarbon chain towards water

answer is C.

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Detailed Solution

Soaps and detergents behave like true solutions at low concentrations but form colloids above Critical micelle concentration(CMC) which is 10-4M-10-3M due to association C17H35COO-Na+ is sodium stearate(soap) C17H35 part is Hydrophobic(nonpolar) part(tail) COO-part is Hydrophilic(polar) part(head).At low concentration;C17H35COO-Na+ ions present on surface with COO- groups in water and C17H35 chains staying away and remain at the surface At or above CMC the polar part (or) the anion part ( COO-)  are pulled into the bulk  where they aggregate to form spherical shape with the C17H35   part(non polar) towards the centre of the sphere and COO- part remaining outward on the surface of the sphere, Micelles are formed due to association above CMC ;  The Hydrophobic part dissolves the grease deposit and  hydrocarbon chain is hydrophobic , anionic part is hydrophilic
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