In a solid 'AB' having the NaCl structure, 'A' atoms occupy the corners of the cubic unit cell. If all the face- centred atoms along one of the axes are removed, then the resultant stoichiometry of the solid is
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a
AB2
b
A2B
c
A4B3
d
A3B4
answer is D.
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Detailed Solution
There were 6A atoms on the face-centres. Removing face-centred atoms along one of the axes means removal of 2A atoms. Now, number of A atoms per unit cell =8×18+4×12=3 (Corners +Face centres) Number of B atoms per units cell =12×14(edge centred)+1 =4(body centred) Hence the resultant stoichiometry is A3B4
In a solid 'AB' having the NaCl structure, 'A' atoms occupy the corners of the cubic unit cell. If all the face- centred atoms along one of the axes are removed, then the resultant stoichiometry of the solid is