Solid AB has the NaCl structure. Atom A occupy the corners of the cubic unit cell. If all the face centered atoms along one of the axes are removed, then the resultant stoichiometry of the solid is
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a
AB2
b
A2B
c
A4B3
d
A3B4
answer is D.
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Detailed Solution
Given solid AB has NaCl structure A+≡Na+−Face centre + corners B−− Cl−− BodyCentre+Edge centers ⇒ A4B4 but Face centers along one axis i.e., 2×12=1 are removed ∴ formulae is A3B4