A solid is made of two elements X and Z. The atoms Z are in CCP arrangement while the atoms X occupy all the tetrahedral sites. What is the formula of the compound?
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a
XZ
b
XZ2
c
X2Z
d
X2Z3
answer is C.
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Detailed Solution
Tetrahedral sites are twice as compared to octahedral sites, then the ratio of X and Z is 2 : 1. Hence formula of the compound X2Z ORZ-ccp arrangementZ (Coordination number) for ccp = 4 = Number of Z atomsNumber of tetrahedral holes = 2×ZC.N = 2×4 = 8Since X occupies tetrahedral holes,therefore Number of atoms of X = 8 Z : X = 4 : 8 = 1 : 2 ⇒X2Z
A solid is made of two elements X and Z. The atoms Z are in CCP arrangement while the atoms X occupy all the tetrahedral sites. What is the formula of the compound?