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In solid state PCl5 is a :

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a
covalent solid
b
octahedral structure
c
ionic solid with [PCl6]+ octahedral and [PCl4]–  tetrahedral
d
ionic solid with [PCl4]+ tetrahedral and [PCl6]–  octahedral

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detailed solution

Correct option is D

In solid state PCl5 prefer to exist as oppositively charged ions like[ PCl4 ]+is tetrahedral and[ PCl6]-   is octahedral.

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Similar Questions

Statement-I: All P-CI bonds in PCI5 are equal in length.

Statement-II: In vapour state PCl5 (PCI4)+ (PCI6) .


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