Q.
In solid state PCl5 is a :
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a
covalent solid
b
octahedral structure
c
ionic solid with [PCl6]+ octahedral and [PCl4]– tetrahedral
d
ionic solid with [PCl4]+ tetrahedral and [PCl6]– octahedral
answer is D.
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Detailed Solution
In solid state PCl5 prefer to exist as oppositively charged ions like[ PCl4 ]+is tetrahedral and[ PCl6]- is octahedral.
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