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Ionic equilibrium

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By Expert Faculty of Sri Chaitanya
Question

The solubility of Ag2CO3 in water at 25°C is 1×10-4 mole / litre. The solubility in 0.01 M Na2CO3 solution is x × 10-5 where x is ________.

Moderate
Solution

Na2CO32Na+2×0.01+CO320.01 Ag2CO32Ag++CO32                        (x+0.01)0.01 Ksp=4x2(0.01) Ksp=4s3=4×1012=4x2(0.01)x=105


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