The solubility of AgCl in 0.1M NaCl is (Ksp of AgCl = 1.2 × 10–10)
0.1M
1.2 x 10-5
1.095 x 10-5
1.2 x 10-9
Solubility of AgCl will be suppressed in presence of NaCl due to commonion effect and the following equilibria gets established.
AgCl(s)⇌AgClS'(aq)→Ag+S'(aq)+C '-S+0.1(aq)
NaCl→Na+(aq)+Cl-0.1(aq)
Ksp=S'+0.1×S'
⇒1.2×10-10=10-1×S'
⇒S'=1.2×10-9