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Q.

Solubility of AgCl in water, 0.01 M CaCl2, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3 and S4 respectively, then

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a

S1 > S2  > S3  > S4

b

S1 > S3  > S2  > S4

c

S1 > S2  = S3  > S4

d

S1 > S3  > S4  < S2

answer is B.

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Detailed Solution

AgCl  ⇌   Ag+   +  Cl-In   CaCl2CaCl2  ⇌   Ca+2   +  2Cl-0.01               0.01         2 x 0.01In NaClNaCl  ⇌   Na+   +  Cl-0.01           0.01          0.01  In   AgNO3AgNO3  ⇌   Ag+   +  NO3¯0.05               0.05          0.05common ion effect is maximum in  AgNO3So,  S1 > S3  > S2  > S4
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