Q.
Solubility of AgCl in water, 0.01 M CaCl2, 0.01 M NaCl and 0.05 M AgNO3 are S1, S2, S3 and S4 respectively, then
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a
S1 > S2 > S3 > S4
b
S1 > S3 > S2 > S4
c
S1 > S2 = S3 > S4
d
S1 > S3 > S4 < S2
answer is B.
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Detailed Solution
AgCl ⇌ Ag+ + Cl-In CaCl2CaCl2 ⇌ Ca+2 + 2Cl-0.01 0.01 2 x 0.01In NaClNaCl ⇌ Na+ + Cl-0.01 0.01 0.01 In AgNO3AgNO3 ⇌ Ag+ + NO3¯0.05 0.05 0.05common ion effect is maximum in AgNO3So, S1 > S3 > S2 > S4
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