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Q.

Solubility of the alkaline earth metal sulphates in water decreases in the sequence

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a

Sr>Ca>Mg>Ba

b

Ba>Mg>Sr>Ca

c

Mg>Ca>Sr>Ba

d

Ca>Sr>Ba>Mg

answer is C.

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Detailed Solution

Solubility of alkaline earth metal sulphates decreases down the group because hydration energy decreases. In the sulphates and carbonates of second group, lattice enthalpy down the group almost remains constant whereas hydration enthalpy decreases, solubility decreases
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