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Q.

A solution contains non-volatile solute of molecular mass M2. Which of the following can be used to calculate the molecular mass of solute in terms of osmotic pressure? (m2=mass of solute, V = volume of solution, π=osmotic pressure)

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a

M2=(m2π)VRT

b

M2=(m2V)RTπ

c

M2=(m2V)πRT

d

M2=(m2V)πRT

answer is B.

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Detailed Solution

We know, π=CRTπ=nVRT;   πV=m2M2RT
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