The solution which show large positive deviation from Raoult's law form
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a
maximum boiling azeotrope at a specific composition
b
maximum freezing azeotrope at a specific composition
c
minimum boiling azeotrope at a specific composition
d
minimum freezing azeotrope at a specific composition
answer is A.
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Detailed Solution
Only non-ideal solutions form azeotropic mixtures (constant boiling mixtures). Among the given, only CCl4 and CHCI3 form non-ideal solution, thus they form azeotropic mixture.