A solution will freeze when

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Vapour pressure of pure solvent is equal to atmospheric pressure.

Vapour pressure of the solution is equal to vapour pressure of pure solvent

Vapour pressure of solution is equal to atmospheric pressure

Vapour pressure of pure solvent is equal to vapour pressure of the pure solid solvent

answer is D.

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Detailed Solution

Freezing point is the temperature at which liquid and solid phase of a substance are in equillibrium. At this temperature both liquid and solid solvent have same vapour pressure.

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