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Q.

A solution will freeze when

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a

Vapour pressure of pure solvent is equal to atmospheric pressure.

b

Vapour pressure of the solution is equal to vapour pressure of pure solvent

c

Vapour pressure of solution is equal to atmospheric pressure

d

Vapour pressure of pure solvent is equal to vapour pressure of the pure solid solvent

answer is D.

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Detailed Solution

Freezing point is the temperature at which liquid and solid phase of a substance are in equillibrium. At this temperature both liquid and solid solvent have same vapour pressure.
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A solution will freeze when