Q.

The solution with highest vapour pressure of the following is

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a

0.2 m sucrose

b

0.15 m sodium chloride

c

0.125 m sodium sulphate

d

0.3 m urea

answer is A.

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Detailed Solution

Effective concentrations;  0.2m sucrose(0.2m×1);  0.15m NaCl(0.15m×2);  0.125m Na2SO4(0.125m×3);    0.3m urea (0.3m×1); LVP ∝molality; VP of  3<2=4<1
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