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Q.

Some statements about d- block elements and their compounds are given below. False statement among the following  is

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a

Oxidation state of ‘Cr’ in CrO4-2  and Cr2O7-2  is same

b

Interstitial compounds  are stoichiometric compounds formed when small atoms like H, C, B, N are trapped in the lattice  of transition elements

c

Catalytic activity of transition metals is due to their ability to exhibit multiple (variable) oxidation states and to form complexes

d

CoF3 is stable due high lattice energy whereas VF5 is stable due to high bond dissociation enthalpy

answer is B.

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Detailed Solution

Interstitial compounds,1) Non-stoichiometric 2) Neither ionic nor covalent 3) Oxidation state doesn’t correspond to true chemical compound 4) Hard 5) High MP 6) Chemically inert 7) Metallic
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