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Q.

Some statements about Reimen-Tiemann reaction involving phenol and chloroform are given below. False statement is

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a

Intermediate formed is

b

Electrophile is C. .Cl2

c

Minor product is para-hydroxy benzaldehyde

d

It is a nucleophilic substitution reaction of phenol

answer is D.

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Detailed Solution

CHCl3+OH-→ CCl3-+H2O; CCl3-→ C..Cl2+Cl-; It is an electrophilic substitution, the electrophile is C..Cl2 ;Minor product is p-hydroxy benzaldehyde. Salicylaldehyde stabilizes due to chelation
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Some statements about Reimen-Tiemann reaction involving phenol and chloroform are given below. False statement is