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Q.

The specific conductance of a saturated solution of silver bromide is k scm-1. The limiting ionic conductivity of Ag+ and Br- ions are x and y, respectively The solubility of silver bromide in gL-1 is : (molar mass of AgBr = 188)

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a

κ×1000x−y

b

κx+y×188

c

κ×1000×188x+y

d

x+yκ×1000188

answer is C.

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Detailed Solution

Λm=κM×1000;(x+y)=κM×1000⇒M=1000×κ(x+y)  Solubility  in gL−1=κ×1000×188x+y
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The specific conductance of a saturated solution of silver bromide is k scm-1. The limiting ionic conductivity of Ag+ and Br- ions are x and y, respectively The solubility of silver bromide in gL-1 is : (molar mass of AgBr = 188)