Q.

A spherical balloon of 21 cm diameter is to be filled up with hydrogen at N.T.P. from a cylinder containing the gas at 20 atmospheres at 27 ºC. If the cylinder can hold 2.82 liters of water, calculate the number of balloons that can be filled up.

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answer is 10.

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Detailed Solution

No. of balloons that can be filled=V of H2 available V of one balloon Calculation of total volume of hydrogen in the cylinder at N.T.P.P1 V1 T1=P2 V2 T2P1 = 1 atm                      P2 = 20 atm  V1 = ?                              V2 = 2.82 l  T1 = 273 K                      T2 = 273 + 27 = 300 ∴V1=20×2.82×273300×1=51.3241=51324 mLActual volume to be transferred into balloons = 51324 – 2820 mL = 48504 mL [∵ 2820 mL of H2 will remain in cylinder] Volume of one balloon =43πr3=43×227×2123∵r= diameter 2= 4851 mL = 4.851LNo. of balloons that can be filled up=485044851=9.999≈10
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