First slide
Crystal lattices and unit cells
Question

A spinel is an important class of oxides consisting of two types of metal ions with the oxide ions arranged in ccp layers. The normal spinel has one-eighth of the tetrahedral holes occupied by one type of metal ion and one-half of the octahedral holes occupied by another type of metal ion. Such a spinel is formed by Mg2+,Al3+ and O2. The neutrality of the crystal is being maintained. Antispinels will differ in arrangements among cations, but anions will be still fcc . 

Moderate
Question

The formula of the spinel is:  

Solution

Mg+2 is in tetrahedral hole, and two Al+3 ions in half of octahedral holes constituting a total charge of +8

Question

 Type of hole occupied by Al3+ ions in inverse spinel will be 

Solution

in inverse spinel M+3 occupy one in tetrahedral hole and one in octahedral hole

Question

Type of hole occupied by Mg2+ ions is:

Solution

always occupy tetrahedral hole either in spinel or antispinel .

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