The stability of carbanion in the following1) 2) 3) 4)
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a
4 > 2 > 1 > 3
b
4 > 1 > 2 > 3
c
1 > 4 > 2 > 3
d
1 > 2 > 3 > 4
answer is C.
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Detailed Solution
As the % of S-character increases, spherical nature of hybridised orbital increases, closeness of electron cloud towards the nucleus increases, and hence Electronegativity of carbon increaseshence the stabilisation of -ve charge on carbon increases,-IE group increases the stability of carbanion+IE groups decreases the stability of carbanion.As the carbon chain length increases, Its +IE strength increases, hence the stability of carbanion decreases.