Stability of the species Li2, Li2– and Li2+ increases in the order of :
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a
Li2 < Li2– < Li2+
b
Li2– < Li2 < Li2+
c
Li2 < Li2+ < Li2–
d
Li2– < Li2+ < Li2
answer is D.
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Detailed Solution
Li2 = kkσ2s2 Bond order = Li2 > Li+2 = Listability order Li2>Li2+>Li2-when two molecular species have same bond order then the species with maximum number of electrons in antibonding molecular orbitals is less stable. Number of ABMO electrons in Li2-= 3Number of ABMO electrons in Li2+= 2